调整井固井用低温早强防窜乳液的研究与应用
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1.中国石油集团大庆钻探工程有限公司工程技术研究院,黑龙江 大庆 163000;2.多资源协同陆相页岩油绿色开采全国重点实验室,黑龙江 大庆 163000

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TE256+.6;P634

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Research and application of low-temperature and early-strength anti-diversion emulsion for adjustment well cementing
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1.Engineering Technology Research Institute, CNPC Daqing Drilling Engineering Company Limited, Daqing Heilongjiang 163000, China;2.State Key Laboratory of Continental Shale Oil, Daqing Heilongjiang 163000, China

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    摘要:

    大庆油田受长期注水调整开发影响,地下压力系统复杂,平面区域的异常高压区广泛分布,同时油层具有埋藏浅、环境温度低等特点。在固井环节,水泥浆受低温环境影响,水化速率下降,浆体结构发展缓慢,另外水泥浆在胶凝过程中易被地层高压流体侵入,导致水泥环的封固能力下降。本文从“晶核诱导”促进水泥水化理论出发,利用化学沉淀法制备水化硅酸钙溶胶早强剂(记为DQZ-1),其加量为2%~10%时40 ℃×8 h水泥石抗压强度较净浆提高39%~153%。微观分析DQZ-1加速水泥水化产物的生成,低温环境早强效果良好。为了增强水泥浆体系低温早强与防窜性能,添加水化硅酸钙与胶乳组分,针对两者接触发生的破乳、沉降分层、稠度高等问题,研选聚羧酸盐MD,使水泥浆维持低初始稠度的同时早强效果明显。研选高聚物溶胶X,使体系拥有良好的防沉降性能,在合理配伍后,制备出一种性能稳定的早强防窜乳液复合剂(记为DZK)。该复合剂可促进油井水泥水化,生成更多的水化产物,水泥浆性能系数SPN值小于3,且静胶凝强度过渡时间较净浆缩短81%。低温早强防窜乳液复合剂在大庆油田应用23口调整井,固井质量优质率100%,油层优质井段比例达96.3%,取得良好的试验效果。

    Abstract:

    Due to long-term water injection for development adjustment in the Daqing Oilfield, the underground pressure system has become complex, with extensive distribution of abnormally high-pressure zones within the formation. Additionally, the oil reservoirs are characterized by shallow burial depth and low ambient temperatures. These conditions reduce the hydration rate and slow down the structural development of cement slurry during the cementing process, as it is affected by low-temperature environments. Consequently, during the gelling process, the cement slurry is prone to invasion by high-pressure formation fluids, resulting in compromised sealing capacity of the cement sheath. Based on the “crystal nucleus induction” theory, this study synthesized hydrated calcium silicate using a chemical precipitation method to prepare a hydrated calcium silicate sol accelerator (designated as DQZ-1). Evaluation showed that with a DQZ-1 dosage of 2%~10% , the 8-hour compressive strength of cement cured at 40°C increased by 39%~153% compared to neat slurry. Microscopic analysis confirmed that DQZ-1 accelerated the formation of cement hydration products, demonstrating excellent early-strength performance in low-temperature environments. To enhance both the low-temperature early strength and anti-channeling properties of the cement slurry system, hydrated calcium silicate and latex components were incorporated. However, issues such as demulsification, settling stratification, and high slurry consistency arose due to their interaction. To address these, polycarboxylate MD was selected, enabling the cement slurry to maintain low initial consistency while achieving significant early strength. Additionally, a polymer colloid X was chosen to impart excellent anti-settling properties to the system. Through rational formulation, a stable early-strength and anti-channeling emulsion composite (designated as DZK) was developed. This composite promotes oil well cement hydration, generating more hydration products. The cement slurry’s performance coefficient (SPN) was lower than 3, and the static gel strength transition time was shortened by 81% compared to the neat slurry. The low-temperature early-strength and anti-channeling emulsion composite was field-tested in 23 adjustment wells in the Daqing Oilfield. It achieved a 100% cementing quality excellence rate, with 96.3% of the oil-bearing sections rated as excellent, demonstrating outstanding field application results.

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引用本文

翟翔宇.调整井固井用低温早强防窜乳液的研究与应用[J].钻探工程,2025,52(4):81-88.
ZHAI Xiangyu. Research and application of low-temperature and early-strength anti-diversion emulsion for adjustment well cementing[J]. Drilling Engineering, 2025,52(4):81-88.

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  • 收稿日期:2025-03-26
  • 最后修改日期:2025-05-16
  • 录用日期:2025-05-20
  • 在线发布日期: 2025-07-04
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